张蓉

个人信息Personal Information

高级工程师

硕士生导师

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学

办公地点:理工西部校区实验楼F308

联系方式:rzhang@dlut.edu.cn

电子邮箱:rzhang@dlut.edu.cn

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Silver(I)-catalyzed denitrative trifluoromethylation of beta-nitrostyrenes with CF3SO2Na

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论文类型:期刊论文

发表时间:2016-10-19

发表刊物:TETRAHEDRON LETTERS

收录刊物:SCIE、Scopus

卷号:57

期号:42

页面范围:4705-4708

ISSN号:0040-4039

关键字:Trifluoromethylation; Denitrative coupling reaction; Stereoselectivity; Ag(I)-catalyzed

摘要:A novel and convenient approach to the synthesis of substituted beta-trifluoromethyl styrenes via a silver(I)-catalyzed denitrative trifluoromethylation with CF3SO2Na under relatively mild conditions has been developed. This protocol delivered excellent stereoselectivity and showed wide substrate tolerance. (C) 2016 Elsevier Ltd. All rights reserved.