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个人信息Personal Information
高级工程师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学
办公地点：理工西部校区实验楼F308
联系方式：rzhang@dlut.edu.cn
电子邮箱：rzhang@dlut.edu.cn
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Copper/Silver-Mediated Decarboxylative Trifluoromethylation of alpha,beta-Unsaturated Carboxylic Acids with CF3SO2Na
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论文类型：期刊论文
发表时间：2014-03-01
发表刊物：SYNTHESIS-STUTTGART
收录刊物：SCIE、EI、Scopus
卷号：46
期号：5
页面范围：607-612
ISSN号：0039-7881
关键字：fluorine; transition metals; copper; catalysis; radicals
摘要：A copper/silver-catalyzed decarboxylative trifluoromethylation of alpha,beta-unsaturated carboxylic acids with CF3SO2Na was performed under relatively mild conditions. The reaction shows high E/Z selectivity and wide substrate tolerance. Ag2CO3 plays an important role in promoting the decarboxylation process.