- Magnolol-based bio-epoxy resin with acceptable glass transition temperature, processability and flame retardancy
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- 论文类型： 期刊论文
- 发表时间： 2020-05-01
- 发表刊物： CHEMICAL ENGINEERING JOURNAL
- 收录刊物： EI、SCIE
- 卷号： 387
- ISSN号： 1385-8947
- 关键字： Magnolol; Biomass; Epoxy resin; Intrinsic flame retardancy; High performance
- 摘要： Development of sustainable bio-based epoxy resins having better comprehensive properties than available petroleum-based epoxy resins is of paramount importance for alleviation of energy pressure and enrichment of the potent category of high-performance epoxy resins. In this study, a fully bio-based epoxy resin precursor (DGEM) was synthesized from a naturally occurring magnolol through a highly efficient one step process. The bio-based epoxy resin obtained was then cured with 4, 4'-diaminodiphenyl sulfone (DDS) and compared to the petroleum-based commercial diglycidylether of bisphenol A (DGEBA). After curing with DDS, DGEM/DDS showed higher glass transition temperature than DGEBA/DDS which was 279 degrees C and 231 degrees C, respectively. The char yield (in N-2), storage modulus and flexural modulus of the former were 1.9-fold, 47.5%, and 41.3% higher than those of the latter, respectively. Interestingly, bio-based epoxy resin of DGEM exhibited excellent processability with extremely low viscosity of 0.155 Pa.s at room temperature and a broader processing window than DGEBA/DDS as well. To exhibit such an excellent processability is very rare for high-performance epoxy resins. In addition, the cured DGEM/DDS also showed outstanding intrinsic flame retardancy, which passed the V-0 rate of UL-94 test. This study offers an opportunity to prepare bio-based epoxy resins with better properties than DGEBA and exhibits great promise in cuffing-edge applications.
