解茂昭

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:北京航空学院

学位:硕士

所在单位:能源与动力学院

电子邮箱:xmz@dlut.edu.cn

扫描关注

论文成果

当前位置: 中文主页 >> 科学研究 >> 论文成果

Development of a skeletal mechanism for diesel surrogate fuel by using a decoupling methodology

点击次数:

论文类型:期刊论文

发表时间:2015-10-01

发表刊物:COMBUSTION AND FLAME

收录刊物:SCIE、Scopus

卷号:162

期号:10

页面范围:3785-3802

ISSN号:0010-2180

关键字:Diesel surrogate model; Skeletal oxidation mechanism; Decoupling methodology

摘要:A diesel surrogate fuel model was developed by including n-decane, iso-octane, methylcyclohexane (MCH), and toluene, which represents the n-paraffins, iso-paraffins, cycloalkanes, and aromatic hydrocarbons in diesel fuel, respectively. The proportions of the components in the surrogate model were determined with special focus on reproducing the chemical characteristics of diesel fuel and less emphasis on its physical characteristics. Then, a decoupling methodology was employed to construct a skeletal oxidation mechanism for the diesel surrogate model, in which the oxidation of small molecules is described in detail, while extremely simplified mechanisms are used for the oxidation of large molecules. The final skeletal mechanism for the diesel surrogate fuel consists of 70 species and 220 reactions without considering cross reactions of the fuel components. The mechanism was extensively validated based on various fundamental experiments for the single components and their mixtures, as well as for practical diesel fuel under wide operating conditions. The predicted ignition delay in shock tubes and the primary species concentrations in jet stirred reactors, flow reactors, and premixed laminar flames agree with the measurements reasonably well, which confirms that the assumption of neglecting the co-oxidation reactions is reasonable. The flame propagation and extinction characteristics are also well reproduced by the mechanism due to the employment of the detailed mechanism for the low-carbon-number molecules. (C) 2015 The Combustion Institute. Published by Elsevier Inc. All rights reserved.