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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 现任大连理工大学化工学院教授、博士生导师。同时担任“膜科学与技术”期刊编委，膜学会理事（筹），膜工业协会工程与应用专业委员会及特种分离膜专业委员会委员、中国兵工学会活性炭测试分析与应用研究分会委员等。
性别：男
毕业院校：大连工学院
学位：硕士
所在单位：化工学院
学科：化学工艺. 膜科学与技术. 功能材料化学与化工
办公地点：化工综合楼A201
联系方式：微信/电话 13500711370
电子邮箱：wangth@dlut.edu.cn
A fixed-bed electrochemical reactor with nano-TiO2 loading flat-sheet carbon membrane as anode for phenolic wastewater treatment
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论文类型：期刊论文
发表时间：2018-06-01
发表刊物：DESALINATION AND WATER TREATMENT
收录刊物：SCIE
卷号：118
页面范围：113-119
ISSN号：1944-3994
关键字：TiO2/flat-sheet carbon membrane; Fixed-bed electrochemical reactor (FBER); Electrochemical oxidation; Phenolic wastewater treatment; Chemical oxygen demand (COD)
摘要：Nano-TiO2 loading flat-sheet microporous carbon membranes with four different thicknesses (4.9-10.3 mm) were prepared and employed as an anode to constitute fixed-bed electrochemical reactor (FBER) for phenolic wastewater treatment. Electroanalytic measurements were used to investigate the electrochemical properties of TiO2/carbon membranes. Results showed that the TiO2/carbon membrane with a thickness of 10.3 mm exhibited the best electrochemical performance. The peak current, effective surface area, charge transfer resistance (R-CT), and the diffusion coefficients obtained from TiO2/carbon membrane with a thickness of 10.3 mm were 7.3 mA, 4.74 cm(2), 2.49 Omega, and 6.88 x 10(-3) cm(2)/s, respectively. Meanwhile, the thickness of carbon membrane electrode is also closely related to its hydrodynamic resistance and the permeability. Further, the removal rates of phenol and chemical oxygen demand (COD) obtained from TiO2/carbon membrane with a thickness of 10.3 mm under the operating conditions of 10.0 mmol/L phenolic wastewater, residence time of 7.8 min, and current density of 1.0 mA/cm(2) were up to 89.3% and 97.5%, respectively. Moreover, the energy consumption of FBER was only 0.36 kWh/kg COD. FBER also demonstrated an excellent stability.