张淑芬

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教授

博士生导师

硕士生导师

任职 : 化学工程与技术一级学科点点长

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工. 有机化学

办公地点:大连市高新区凌工路2号西部校区化工楼E434房间

联系方式:0411-84986265

电子邮箱:zhangshf@dlut.edu.cn

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Thermoresponsive cellulose ether and its flocculation behavior for organic dye removal

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论文类型:期刊论文

第一作者:Tian, Ye

通讯作者:Ju, BZ (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.

合写作者:Ju, Benzhi,Zhang, Shufen,Hou, Linan

发表时间:2016-01-20

发表刊物:CARBOHYDRATE POLYMERS

收录刊物:SCIE、EI、PubMed

卷号:136

页面范围:1209-1217

ISSN号:0144-8617

关键字:Cellulose ether; Thermoresponsivity; Organic dye; Flocculation; Recycling

摘要:A thermoresponsive polymer, 2-hydroxy-3-butoxypropyl hydroxyethyl cellulose (HBPEC), was prepared by grafting butyl glycidyl ether (BGE) onto hydroxyethyl cellulose (HEC). The lower critical solution temperature (LCST) and critical flocculation temperature (CFT) of HBPEC were varied by changing the molar substitution (MS) and salt concentrations. Transmission electron microscopy (TEM) images and fluorescence spectroscopy showed that HBPEC can assemble into micelles. Additionally, using Nile Red as a model dye, the performance of HBPEC for the removing Nile Red from aqueous solutions via cloud point extraction procedures was investigated in detail. The encapsulation behavior of dye in the aqueous solution of HBPEC was studied by fluorescence spectroscopy and fluorescence microscope. The experimental results indicated that 99.4% of dye was removed from the aqueous solutions, and the HBPEC was recycled and reused easily, Furthermore, the recycle efficiency (RE) and maximum loading capacity portrayed little loss with the number of cycles. (C) 2015 Elsevier Ltd. All rights reserved.