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论文类型：期刊论文

发表时间：2019-10-01

发表刊物：BULLETIN OF THE KOREAN CHEMICAL SOCIETY

收录刊物：EI、SCIE

卷号：40

期号：10

页面范围：997-1001

ISSN号：1229-5949

关键字：Au nanoparticles; Stabilization; 4-Nitrobenzaldehyde; Polymers; Selective hydrogenation

摘要：We report the facile synthesis of small gold nanoparticles stabilized by carbon nanospheres (Au@C) for highly active and selective hydrogenation of 4-nitrobenzaldehyde. The formation of such a Au@C unique structure can be attributed to the high distribution of Au(III) species in the melamine-formaldehyde resin nanospheres, which were formed via the coordination of Au(III) with the abundant imino groups of melamine-formaldehyde pre-polymer. After the subsequent condensation and confined in situ reduction, small gold nanoparticles, and carbon nanospheres were formed simultaneously. Under the reaction conditions of 80 degrees C and 1.6 MPa, 99.3% conversion and >99% selectivity were achieved for the hydrogenation of 4-nitrobenzaldehyde to 4-aminobenzaldehyde.