个人信息Personal Information
教授
博士生导师
硕士生导师
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 高分子化学与物理. 精细化工
办公地点:西部校区知化楼 D-403
联系方式:大连理工大学西部校区化工学院
电子邮箱:xblu@dlut.edu.cn
个人简介Personal Profile
吕小兵,教授、博士生导师。
1997年于中国科学技术大学获理学硕士学位,师从方月娥教授;2002年在大连理工大学化工学院获得工学博士学位,师从何仁教授,并于同年在精细化工国家重点实验室开展独立研究工作,2005年破格晋升为教授、博士生导师。2005年获中国化学会“青年化学奖”、霍英东教育基金会青年教师奖和教育部自然科学二等奖;2006年获国家杰出青年科学基金;2007年获中国青年科技奖;2009年获中国石化协会青年科技突出贡献奖,并入选国家百千万人才工程;2011年获教育部长江学者特聘教授,2013年《小分子活化与仿生催化》教育部创新团队负责人,2017年获滚动支持;2014年获科技部中青年科技创新领军人才称号;2015年获教育部自然科学一等奖;2016年入选中组部第二批国家万人计划;2020年获首届中国化学会京博科技创新奖。
主要研究方向:
1. 立体选择性可控配位催化聚合
2. 主链手性高分子合成及其立体相互作用
3. 多手性和多层次手性高分子构筑
4. 可持续高分子(降解性和可化学循环高分子)
正在承担的课题:
1. 国家基金委重点国际合作项目:结晶性和功能化聚酯的创制
2. 国家基金委 “高分子材料变革性合成与结构创新”原创探索计划项目:高分子立体汇聚
3. 科技部国家重点研发计划子课题:可循环聚碳酸酯和聚酯的合成
4. 国家基金委多层次手性物质的精准构筑重大研究计划集成项目:高分子多层次手性结构高效精准构筑
近几年代表性研究论文:
1. Yong-Qiang Teng, Bai-Hao Ren, Ye Liu,* Jie Gao, Wei-Min Ren, and Xiao-Bing Lu*. Innovative Approach to Chiral Polyurethanes: Asymmetric Copolymerization with Isocyanates. Angew. Chem. Int. Ed. 2024, 63, e202404186.
2. Guang-Hui He, Bai-Hao Ren, Shang Wang, Ye Liu, and Xiao-Bing Lu*. Sequence Control in Asymmetric Terpolymerizations of meso-Epoxides, CO2, and Phthalic Anhydride: Unprecedented Statistical Ester–Carbonate Distributions. Angew. Chem. Int. Ed. 2023, 62, e202304943. (Hot paper)
3. Jie Li,* Qiu-Yu Zhang,* and Xiao-Bing Lu*. Azopolyesters with Intrinsic Crystallinity and Photoswitchable Reversible Solid-to-Liquid Transitions. Angew. Chem. Int. Ed. 2023, 62, e202311158. (Very important paper)
4. Yi-Ning Li, Ye Liu, Han-Han Yang, Wen-Fu Zhang, and Xiao-Bing Lu*. Intramolecular Partners in Asymmetric Catalysis Copolymerization: Highly Enantioselective and Controllable at Enhanced Temperatures and Low Loadings. Angew. Chem. Int. Ed. 2022, 61, e202202585. (Hot paper)
5. Yan Yu, Bang Gao, Ye Liu,* and Xiao-Bing Lu*. Efficient and Selective Chemical Recycling of CO2-Based Alicyclic Polycarbonates via Catalytic Pyrolysis. Angew. Chem. Int. Ed. 2022, 61, e202204492. (Hot paper)
6. Wen-Bing Li, Bai-Hao Ren, Ge-Ge Gu, and Xiao-Bing Lu*. Controlled Random Terpolymerization of β-Propiolactone, Epoxides, and CO2 via Regioselective Lactone Ring Opening. CCS Chem. 2022, 4, 344–355.
7. Guang-Hui He, Bai-Hao Ren, Shi-Yu Chen, Ye Liu, and Xiao-Bing Lu*. Enantioselective, Stereoconvergent Resolution Copolymerization of Racemic cis-Internal Epoxides and Anhydrides. Angew. Chem. Int. Ed. 2021, 60, 5994–6002.
8. Jie Li, Meng-Wei Wang, Ye Liu, Wei-Min Ren, and Xiao-Bing Lu*. Photoinduced Reversible Semicrystalline-to-Amorphous State Transitions of Stereoregular Azopolyesters. Angew. Chem. Int. Ed. 2021, 60, 17898–17903. (Hot paper)
9. Jie Li, Ye Liu, Wei-Min Ren, and Xiao-Bing Lu*. Enantioselective Terpolymerization of Racemic- and Meso-Epoxides with Anhydrides for Preparation of Chiral Polyesters. PNAS 2020, 117, 15429–15436.
10. Jie Li, Bai-Hao Ren, Zhao-Qian Wan, Shi-Yu Chen, Ye Liu, Wei-Min Ren, and Xiao-Bing Lu*. Enantioselective Resolution Copolymerization of Racemic Epoxides and Anhydrides: Efficient Approach for Stereoregular Polyesters and Chiral Epoxides. J. Am. Chem. Soc. 2019, 141, 8937–8942.
11. Zhao-Qian Wan, Julie M. Longo, Li-Xin Liang, Hong-Yu Chen, Guang-Jin Hou, Shuai Yang, Wei-Ping Zhang, Geoffrey W. Coates,* and Xiao-Bing Lu*. Comprehensive Understanding of Polyester Stereocomplexation. J. Am. Chem. Soc. 2019, 141, 14780−14787.
12. Zhao-Qian Wan, Wei-Min Ren, Shuai Yang, Ming-Ran Li, Ge-Ge Gu, and Xiao-Bing Lu*. Reversible Transformation between Amorphous and Crystalline States of Unsaturated Polyesters by Cis–Trans Isomerization. Angew. Chem. Int. Ed. 2019, 58, 17636–17640. (Hot paper)
13. Tian-Jun Yue, Ming-Chao Zhang, Ge-Ge Gu, Li-Yang Wang, Wei-Min Ren,* and Xiao-Bing Lu*. Precise Synthesis of Poly(thioester)s with Diverse Structures by Copolymerization of Cyclic Thioanhydrides and Episulfides Mediated by Organic Ammon ium Salts. Angew. Chem. Int. Ed. 2019, 58, 618–623.
4. Jie Li, Bai-Hao Ren, Shi-Yu Chen, Guang-Hui He, Ye Liu, Wei-Min Ren, Hui Zhou, and Xiao-Bing Lu*. Development of Highly Enantioselective Catalysts for Asymmetric Copolymerization of meso-Epoxides and Cyclic Anhydrides: Subtle Modification Resulting in Superior Enantioselectivity. ACS Catal. 2019, 9, 1915−1922.
15. Tian-Jun Yue, Wei-Min Ren,* Li Chen, Ge-Ge Gu, Ye Liu, and Xiao-Bing Lu*. Synthesis of Chiral Sulfur-Containing Polymers: Asymmetric Copolymerization of meso-Epoxides and Carbonyl Sulfide. Angew. Chem. Int. Ed. 2018, 57, 12670–12674.
16. Ye Liu,* Hui Zhou, Jia-Zhi Guo, Wei-Min Ren, and Xiao-Bing Lu*. Completely Recyclable Monomers and Polycarbonate: Approach to Sustainable Polymers. Angew. Chem. Int. Ed. 2017, 56, 4862–4866. (Hot paper)
17. Jie Li, Ye Liu, Wei-Min Ren, and Xiao-Bing Lu*. Asymmetric Alternating Copolymerization of meso-Epoxides and Cyclic Anhydrides: Efficient Access to Enantiopure Polyesters. J. Am. Chem. Soc. 2016, 138, 11493–11496.
18. Ye Liu, Wei-Min Ren, Meng Wang, Chuang Liu, and Xiao-Bing Lu*. Crystalline Stereocomplexed Polycarbonates: Hydrogen Bond Driven Interlocked Orderly Assembly of the Opposite Enantiomers. Angew. Chem. Int. Ed. 2015, 54, 2241–2244. (Very important paper)
19. Ye Liu, Meng Wang, Wei-Min Ren, Yue-Chao Xu, and Xiao-Bing Lu*. Crystalline Hetero-Stereocomplexed Polycarbonates Produced fromAmorphous Opposite Enantiomers Having Different ChemicalStructures. Angew. Chem. Int. Ed. 2015, 54, 7042–7046.
20. Ye Liu, Wei-Min Ren, Wei-Ping Zhang, Rong-Rong Zhao, and Xiao-Bing Lu*. Crystalline CO2-based polycarbonates prepared from racemic catalyst through intramolecularly interlocked assembly. Nat. Commun. 2015, 6, 8594.
21. Ye Liu, Wei-Min Ren, Ke-Ke He, and Xiao-Bing Lu*. Crystalline-gradient polycarbonates prepared from enantioselective terpolymerization of meso-epoxides with CO2. Nat. Commun. 2014, 5, 5687.
22. Ye Liu, Wei-Min Ren, Chuang Liu, Song Fu, Meng Wang, Ke-Ke He, Rong-Rong Li, Rong Zhang, and Xiao-Bing Lu*. Mechanistic Understanding of Dinuclear Cobalt(III) Complex Mediated Highly Enantioselective Copolymerization of meso-Epoxides with CO2. Macromolecules 2014, 47, 7775−7788.
23. Yan-Bo Wang, Yi-Ming Wang, Wen-Zhen Zhang, and Xiao-Bing Lu*. Fast CO2 Sequestration, Activation, and Catalytic Transformation Using N‑Heterocyclic Olefins. J. Am. Chem. Soc. 2013, 135, 11996−12003.
24. Ye Liu, Wei-Min Ren, Jie Liu, and Xiao-Bing Lu*. Asymmetric Copolymerization of CO2 with meso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity. Angew. Chem. Int. Ed. 2013, 52, 11594–11598.
25. Guang-Peng Wu, Wei-Min Ren, Yi Luo, Bo Li, Wen-Zhen Zhang, and Xiao-Bing Lu*. Enhanced Asymmetric Induction for the Copolymerization of CO2 and Cyclohexene Oxide with Unsymmetric Enantiopure SalenCo(III) Complexes: Synthesis of Crystalline CO2-Based Polycarbonate. J. Am. Chem. Soc. 2012, 134, 5682−5688.
26. Xiao-Bing Lu*, Wei-Min Ren, Guang-Peng Wu. CO2 Copolymers from Epoxides: Catalyst Activity, Product Selectivity and Stereochemistry Control. Acc. Chem. Res. 2012, 45, 1721–1735.