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Indexed by:期刊论文

Date of Publication:2014-03-01

Journal:SYNTHESIS-STUTTGART

Included Journals:SCIE、EI、Scopus

Volume:46

Issue:5

Page Number:607-612

ISSN No.:0039-7881

Key Words:fluorine; transition metals; copper; catalysis; radicals

Abstract:A copper/silver-catalyzed decarboxylative trifluoromethylation of alpha,beta-unsaturated carboxylic acids with CF3SO2Na was performed under relatively mild conditions. The reaction shows high E/Z selectivity and wide substrate tolerance. Ag2CO3 plays an important role in promoting the decarboxylation process.