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Copper-catalyzed one-pot synthesis of alkynylphophonates

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Indexed by:期刊论文

Date of Publication:2019-01-01

Journal:SYNTHETIC COMMUNICATIONS

Included Journals:SCIE

Volume:49

Issue:5

Page Number:697-703

ISSN No.:0039-7911

Key Words:Alkynylphophonates; copper; haloalkynes; one-pot

Abstract:Copper is found to be an effective catalyst for the preparation of alkynylphophonates. A novel copper-catalyzed one-pot synthesis of alkynylphophonates from terminal alkynes and dialkyl phosphites is developed which involves the haloalkynes intermediates. This method provides a unique and alternative approach to the well-documented oxidative coupling or arylpropiolic acid strategies.
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