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论文类型：期刊论文

发表时间：2017-08-01

发表刊物：Journal of Environmental Chemical Engineering

收录刊物：Scopus、EI

卷号：5

期号：4

页面范围：3348-3353

ISSN号：22133437

摘要：Magnetic amino-reduced graphene oxide was successfully fabricated via a covalent chemical combination method. Fe3O4 was first reacted with polyacrylic acid (Fe3O4-COOH) and then reacted with diethylenetriamine; finally, the amino modified Fe3O4 (Fe3O4-NH2) was introduced as magnetic carrier and reductant to reduce graphene oxide to obtain Fe3O4-rGO. SEM, AFM, FTIR, XRD and XPS analyses were performed to analyze the synthesized materials. The catalytic performance of Fe3O4-rGO was investigated through the bioreduction of p-nitrophenol (p-NP) in the presence of Shewanella sp. CNZ-1. The results showed that p-NP bioreduction could be enhanced in a dose-dependent manner of Fe3O4-rGO. The p-NP reduction rate could achieve 0.92 mmol/(d gcell) in the presence of 25 mg/L Fe3O4-rGO, which was approximately 4.18-fold higher than that lacking Fe3O4-rGO. In addition, the experimental kinetic data of Fe3O4-rGO mediated P-NP bio-reduction fit well with the pseudo-first-order model (R2 > 0.96). These findings indicate that Fe3O4-rGO could be used in designing a bioreactor for enhancing the treatment of p-NP containing wastewater. ? 2017 Elsevier Ltd.