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博士生导师

硕士生导师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

办公地点:大连理工大学西部校区E座421室

联系方式:手机:13998430917

电子邮箱:jubenzhi@dlut.edu.cn

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Foaming Behavior of Dialdehyde Starch Schiff-base Derivatives

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论文类型:期刊论文

发表时间:2013-07-01

发表刊物:TENSIDE SURFACTANTS DETERGENTS

收录刊物:SCIE、EI、Scopus

卷号:50

期号:4

页面范围:270-276

ISSN号:0932-3414

关键字:Dialdehyde starch-aniline Schiff-base; foaming behavior; surface activity

摘要:A foamable dialdehyde starch-aniline Schiff-base (DAS-AN) was synthesized by the reaction of dialdehyde starch (DAS) and oil-soluble aniline in a homogeneous dimethyl sulfoxide system under N-2 atmosphere. The DAS-ANs were characterized by gel permeation chromatography (GPC), Fourier-transform infrared spectroscopy (FT-IR) and NMR spectroscopy. Their foaming behavior and surface tension were investigated. Foaming power and stability tests were performed for solutions of DAS-ANs with different degrees of substitutions with aniline (DSAN) and concentrations. The maximum foaming power was 2.6 times the initial solution volume of the foam test in 450 mg . L-1 CaCO3 aqueous solution. The most stable foams only decreased by 6% in volume in deionized water after 20 min.