唐炳涛

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工

办公地点:大连理工大学西部校区综合实验楼E424

联系方式:tangbt@dlut.edu.cn

电子邮箱:tangbt@dlut.edu.cn

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Synthesis of Novel Reactive Disperse Silicon-Containing Dyes and Their Coloring Properties on Silicone Rubbers.

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论文类型:期刊论文

第一作者:Yu Ning

通讯作者:Zhang, SF (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.

合写作者:Zhang Shufen,Tang Bingtao,Ma Wei,Qiu Jinjing

发表时间:2018-01-09

发表刊物:Molecules (Basel, Switzerland)

收录刊物:SCIE、PubMed

卷号:23

期号:1

ISSN号:1420-3049

关键字:coloring,reactive disperse dyes,silicone group,silicone rubber

摘要:Novel red and purple reactive disperse silicon-containing dyes were designed and synthesized using p-nitroaniline and 6-bromo-2,4-dinitro-aniline as diazonium components, the first condensation product of cyanuric chloride and 3-(N,N-diethyl)amino-aniline as coupling component, and 3-aminopropylmethoxydimethylsilane, 3-aminopropylmethyldimethoxysilane, and 3-aminopropyltrimethoxysilane as silicone reactive agents. These dyes were characterized by UV-Vis, H-NMR, FT-IR, and MS. The obtained reactive disperse silicon-containing dyes were used to color silicone rubbers and the color fastness of the dyes were evaluated. The dry/wet rubbing and washing fastnesses of these dyes all reached 4-5 grade and the sublimation fastness was also above 4 grade, indicating outstanding performance in terms of color fastness. Such colored silicone rubbers showed bright and rich colors without affecting its static mechanical properties.