唐炳涛

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工

办公地点:大连理工大学西部校区综合实验楼E424

联系方式:tangbt@dlut.edu.cn

电子邮箱:tangbt@dlut.edu.cn

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High-Performance and Multifunctional Colorimetric Humidity Sensors Based on Mesoporous Photonic Crystals and Nanogels

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论文类型:期刊论文

发表时间:2018-12-05

发表刊物:ACS APPLIED MATERIALS & INTERFACES

收录刊物:SCIE、PubMed、Scopus

卷号:10

期号:48

页面范围:41645-41654

ISSN号:1944-8244

关键字:colorimetric humidity sensors; photonic crystals; nanogels; mesoporous structure; patterning

摘要:Colorimetric sensors, as a key branch of the application of photonic crystals (PCs), brings enthusiasm to scientists to do research. Here, simple mesoporous and structurally colored one-dimensional photonic crystals (1DPCs) constructed by alternating assembly of poly(acrylamide-N,N'-methylene bis(acrylamide)) (P(AM-MBA)) nanogels and TiO2 nanoparticles are reported as high-performance colorimetric humidity sensors. The sensors with bright colors display rapid response to relative humidity (RH) change and reach sensing balance in 0.5 s. By varying RH from 47.0% to 89.3%, stopband of a sensor changes from 426 to 668 nm, almost spanning the whole visible range. Meanwhile, visual sensing of RH possesses good reversibility and repeatability. Moreover, the sensors with delicate patterns are facilely fabricated by partial UV photodegradation of the polymer layers with nano TiO2 as catalyst. The delicate patterns and backgrounds show different colors and change color simultaneously and quickly by varying the ambient humidity. Accurate QR code pattern is also realized on the PC sensor; it is found successful reading of the data is only achieved by increasing RH to realize high color contrast between the code and background. Given their excellent properties, the porous hybrid PCs are promising as high-performance humidity sensors with potential display, decoration, information-storage, and encryption functions.