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Indexed by:期刊论文
Date of Publication:2018-12-04
Journal:CHEMICAL COMMUNICATIONS
Included Journals:SCIE、Scopus
Volume:54
Issue:93
Page Number:13119-13122
ISSN No.:1359-7345
Abstract:Reduction of a thiolate-bridged (FeFeIII)-Fe-II complex leads to the cleavage of an Fe-S bond by the insertion of the methylene unit from CH2Cl2 to give a neutral (FeFeIII)-Fe-II complex with a novel Fe-CH2-S fragment. The structural and electrochemical differences of the alkylated and the non-alkylated Fe2S2 complexes are also examined.
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