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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
Unsupported Nanoporous Gold-Catalyzed Chemoselective Reduction of alpha,beta-Unsaturated Aldehydes Using Formic Acid as Hydrogen Source
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论文类型：期刊论文
发表时间：2017-07-01
发表刊物：ASIAN JOURNAL OF ORGANIC CHEMISTRY
收录刊物：SCIE、Scopus
卷号：6
期号：7
页面范围：867-872
ISSN号：2193-5807
关键字：allylic compounds; chemoselectivity; aldehydes; formic acid; reduction
摘要：A straightforward, highly chemoselective hydrogenation of ,-unsaturated aldehydes was developed using unsupported nanoporous gold (AuNPore) as a heterogeneous catalyst with bio-renewable formic acid (HCO2H) as hydrogen source. Various alpha,beta-unsaturated aldehydes were reduced to their corresponding allylic alcohols in good to high chemical yields with excellent selectivity. AuNPore offers several attractive features as a catalyst, such as high activity and selectivity, easy recyclability, and no leaching.