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教授

博士生导师

硕士生导师

性别:男

毕业院校:日本东北大学

学位:博士

所在单位:化工学院盘锦分院

办公地点:精细化工国家重点实验室E504

电子邮箱:mingbao@dlut.edu.cn

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Carboxylative Coupling of Chloromethyl(hetero)arenes with Allyltrimethoxysilane Catalyzed by Palladium Nanoparticles

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论文类型:期刊论文

发表时间:2017-02-01

发表刊物:ASIAN JOURNAL OF ORGANIC CHEMISTRY

收录刊物:SCIE

卷号:6

期号:2

页面范围:177-183

ISSN号:2193-5807

关键字:arenes; carbon dioxide fixation; multicomponent reactions; palladium; silanes

摘要:The palladium-catalyzed three-component coupling of either (chloromethyl)arenes or (chloromethyl)heteroarenes with allyltrimethoxysilane and carbon dioxide (i.e., a carboxylative Hiyama coupling reaction) successfully produced ,alpha,beta-unsaturated esters in satisfactory to good yields. This reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles (NPs). A reaction mechanism, which includes the formation of an pi-allylpalladium chloride intermediate, has been proposed.