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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
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Rhodium-Catalyzed Oxidative Benzannulation of N-Adamantyl-1-naphthylamines with Internal Alkynes via Dual C-H Bond Activation: Synthesis of Substituted Anthracenes
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论文类型：期刊论文
发表时间：2016-09-02
发表刊物：ORGANIC LETTERS
收录刊物：SCIE、PubMed、Scopus
卷号：18
期号：17
页面范围：4246-4249
ISSN号：1523-7060
摘要：Rhodium-catalyzed oxidative benzannulation of N-adaffianty1-1-naphthylarnines with internal alkynes to produce highly substituted anthracenes in satisfactory to good yields was developed. The annulation reaction proceeded smoothly under mild conditions in the presence of [Cp*RhCl2](2) as the precatalyst and Cu(OAc)(2) as the oxidant.