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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
Carboxylative coupling reaction of five-membered (chloromethyl) heteroarenes with allyltributylstannane catalyzed by palladium nanoparticles
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论文类型：期刊论文
发表时间：2015-12-02
发表刊物：TETRAHEDRON LETTERS
收录刊物：SCIE、Scopus
卷号：56
期号：48
页面范围：6747-6750
ISSN号：0040-4039
关键字：Palladium nanoparticles; Carbon dioxide; Carboxylative coupling
摘要：The palladium-catalyzed three-component coupling reaction of five-membered (chloromethyl) heteroarenes, allyltributylstannane, and carbon dioxide (carboxylative Stille coupling reaction) was successfully conducted to produce beta,gamma-unsaturated esters in satisfactory to good yields. The carboxylative Stille coupling reaction occurred smoothly under mild conditions in the presence of palladium nanopartides through the formation of pi-allylpalladium chloride intermediates. (C) 2015 Elsevier Ltd. All rights reserved.