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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本东北大学
学位：博士
所在单位：化工学院盘锦分院
办公地点：精细化工国家重点实验室E504
电子邮箱：mingbao@dlut.edu.cn
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Highly chemoselective reduction of imines using a AuNPore/PhMe2SiH/water system and its application to reductive amination
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论文类型：期刊论文
发表时间：2015-09-30
发表刊物：TETRAHEDRON
收录刊物：SCIE、Scopus
卷号：71
期号：39,SI
页面范围：7154-7158
ISSN号：0040-4020
关键字：Amine; Imine; Heterogeneous catalysis; Nanoporous gold; Reductive amination
摘要：An unusually strong affinity of unsupported nanoporous gold (AuNPore) towards aldimines and ketimines has been demonstrated. By using PhMe2SiH and water as a hydrogen source and AuNPore as a catalyst, ketimines and aldimines can be reduced to the corresponding amines in high chemical yields under mild conditions. This system was also applied to the reductive amination of aldehydes and ketones. (C) 2014 Elsevier Ltd. All rights reserved.