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论文类型：期刊论文

发表时间：2019-01-01

发表刊物：COORDINATION CHEMISTRY REVIEWS

收录刊物：SCIE、Scopus

卷号：378

期号：,SI

页面范围：151-187

ISSN号：0010-8545

关键字：Werner-type capsule; Confined space effect; Supramolecular catalysis; Thermodynamic constraints; Dynamic behaviors; Electron transfer; Photosynthesis

摘要：The use of small molecules with defined cavities that catalyze unique chemical transformations to emulate enzyme sites have resulted in sustainable catalytic transformation with unprecedented selectivity that proceed under ambient conditions using benign solvents and clean energy. Of these reported host molecules, Werner-type capsules have been of particular interest to researchers because of their structural modifiability and rich chemical properties arising from their uniform cavities. In this review, we focus on the catalytic properties of several important catalytic transformations that have occurred within the confined pockets of these Werner-type capsules with special attention to the aspects that are derived from the 'confined space effect' of these Werner-type capsules. (C) 2017 Elsevier B.V. All rights reserved.