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论文类型：期刊论文

第一作者：Chu, Lin

通讯作者：Zhang, SF (reprint author), Dalian Univ Technol, Key Lab Fine Chem, Dalian 116024, Peoples R China.

合写作者：Niu, Wenbin,Wu, Suli,Ma, Wei,Tang, Bingtao,Zhang, Shufen,Li, Heping,Liu, Zheng

发表时间：2019-05-01

发表刊物：MATERIALS RESEARCH EXPRESS

收录刊物：SCIE

卷号：6

期号：5

ISSN号：2053-1591

关键字：nanospheres; starch; cellulose; polysaccharide; hydrophobic; hydrothermal

摘要：Owing to the simultaneous occurrence of nucleation and nuclei aggregation in nanoprecipitation approach, the preparation of monodisperse nanospheres from polysaccharide remains a great challenge. Herein a two-step approach is presented for size controlled preparation of monodisperse polysaccharide-based nanospheres with PDI of 0.05 from starch acetate (SA). First, the starch acetate nanospheres (SANs) with average size in the range from 100 to 160 nm were produced by a moderate and constant hydrophobic interaction (MCHI) process. Second, based on principle of Ostwald ripening, a facile hydrothermal method was employed to modulate the size of the SANs obtained from the first step, yielding monodisperse nanospheres ranging from 200 to 1400 nm. This two-step method was also successfully applied to the preparation of ethyl cellulose nanospheres, which provided a facile strategy to prepare nanospheres from polysaccharides. Finally, SANs (744 nm) and ECNs (802 nm) were used to fabricate 2D photonic crystals by self-assembly, further verifying high monodispersity of obtained polysaccharide-based nanospheres.