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论文类型：期刊论文

发表时间：2016-05-01

发表刊物：CHINESE CHEMICAL LETTERS

收录刊物：SCIE、ISTIC

卷号：27

期号：5

页面范围：764-768

ISSN号：1001-8417

关键字：Solvothermal synthesis; H2Pc single crystal; Optical properties; Near-infrared; Electroluminescence

摘要：A metal-free purple H2Pc single crystal was synthesized by a facile solvothermal method, and its solubility and near-infrared (NIR) optical properties were also investigated due to its potential applications as a light-emitting layer for OLEDs. The H2Pc single crystal is insoluble in 1-chlorine naphthalene and other organic solvents. It gives a wide absorption in the range from 620 nm to 679 nm and a wide emission in near 922 nm. As an active light-emitting layer, H2Pc was employed to fabricate electroluminescent (EL) devices with a structure of ITO/NPB (30 nm)/Alq(3):H2Pc (30 nm)/BCP (20 nm)/Alq(3) (20 nm)/Al. The emission center is at 936 nm when the H2Pc doping concentration is 20 wt%. The doping concentration strongly governs the emission intensity. When doping concentration decreases from 10 wt% to 1 wt%, the emission intensity remarkably fades, and simultaneously the emission center undergoes a blue shift. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.