Fang Kezhao
Professor Supervisor of Doctorate Candidates Supervisor of Master's Candidates
Gender:Male
Alma Mater:Dalian University of Technology
Degree:Doctoral Degree
School/Department:Dalian University of Technology
Discipline:Port, Coastal and Offshore Engineering
Business Address:Room B304, Ocean Engineering Research Institute
E-Mail:kfang@dlut.edu.cn
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Indexed by:期刊论文
Date of Publication:2002-01-01
Journal:Journal of Natural Gas Chemistry
Included Journals:Scopus
Volume:11
Issue:1-2
Page Number:51-56
ISSN No.:10039953
Abstract:Synthesis of acetic acid by direct oxidation of ethylene on Pd-H4SiW12O40-based catalysts was studied in a fixed-bed integral reactor and a pulse differential reactor. From the performance of the catalysts with different compositions and configurations, acetic acid was predominantly produced via an intermediate of acetaldehyde. The active sites for acetic acid formation existed mainly at the boundaries between the H4SiW12O40 and the Pd particles. The Pd-based catalysts reduced by H2/N2 had higher activities than those reduced by hydrazine, as explained by the degree of Pd dispersion obtained from the characteristics of hydrogen chemical adsorption. Pd-Se-SiW12/SiO2 catalyst with selenium tetrachloride as a precursor was more active than that with potassium selenite, and the acetic acid could be greatly increased by adding a suitable amount of dichloroethane (C2H4Cl2/C2H4 mole ratio = 0.03:1) to the reactants. On all catalysts containing SiW12, a small amount of ethanol was detected, which was almost unchanged by the catalyst composition.
Dr. Kezhao Fang is an associated professor (Phd Supervisor) with the State Key Laboratory of Coastal and Offshore Engineering in Dalian University of Technology. His research interests include (but not limitted to) developing numerical models for ocean and coastal waves, coastal (reef) hydrodynamics, coastal morphology. He is a member of IAHR and an invited reviewer for Journal of Fluid Mechanics, Coastal Engineering, Ocean Engineering, Applied Ocean Research, and etc. He has got a total of more than 80 papers published, the details of the papers also could be found via researchgate:
https://www.researchgate.net/profile/Kezhao_Fang2
