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论文类型：期刊论文

发表时间：2013-06-14

发表刊物：JOURNAL OF MATERIALS CHEMISTRY A

收录刊物：SCIE、EI、Scopus

卷号：1

期号：22

页面范围：6530-6534

ISSN号：2050-7488

摘要：A novel functionalized MOF material, Bronsted acidic ionic liquid (BAIL) confined inside well-defined MIL-101 nanocages, was developed for the first time based on the tandem post-synthetic strategy. The catalytic performance of BAIL confined in MIL-101 material was evaluated by using the acetalization of benzaldehyde with glycol as a probe reaction. The resulting BAIL/MIL-101 material exhibited superior catalytic performance, which is mainly due to the combination of the advantageous merits of ionic liquid catalyst with the desirable microenvironment in the MIL-101 nanocages.