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论文类型： 期刊论文

发表时间： 2016-11-22

发表刊物： Chemistry-An Asian Journal

收录刊物： SCIE、EI、PubMed、Scopus

卷号： 11

期号： 22

页面范围： 3241-3250

ISSN号： 1861-4728

关键字： benzannulation; naphthalene; N-pivaloylaniline; rhodium catalysis

摘要： An efficient method was developed for the synthesis of highly substituted naphthalenes through rhodium-catalyzed oxidative benzannulation of N-pivaloylanilines with internal alkynes. The benzannulation reaction proceeded smoothly through dual C-H bond activation to produce the corresponding highly substituted naphthalene products in satisfactory to good yields.