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    张建军

    • 教授     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:南京大学
    • 学位:博士
    • 所在单位:化学学院
    • 学科:无机化学
    • 办公地点:化工综合楼D411
    • 联系方式:0411-84986036
    • 电子邮箱:zhangjj@dlut.edu.cn

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    A heptanuclear heterotrimetallic [Na2Cr2Tb3] cluster exhibiting single-molecule magnet behavior

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    论文类型:期刊论文

    发表时间:2013-11-01

    发表刊物:INORGANIC CHEMISTRY COMMUNICATIONS

    收录刊物:SCIE、Scopus

    卷号:37

    页面范围:202-205

    ISSN号:1387-7003

    关键字:Heptanuclear; Heterotrimetallic; Maleic acid; Bicapped trigonal bipyramid; Slow relaxation of the magnetization

    摘要:With maleic acid as the ligand, a heterotrimetallic cluster {[Na(H2O)][Na2Cr2Tb3(mu(3)-OH)(6)(L)(6)(H2O)(17)]}center dot 16H(2)O (H2L = maleic acid) (1) bearing a bicapped trigonal bipyramidal [Na2Cr2Tb3] metal skeleton was synthesized and characterized. Magnetic measurements indicate that 1 displays overall ferromagnetic interactions and slow relaxation of the magnetization. (C) 2013 Elsevier B.V. All rights reserved.