张建军
开通时间:..
最后更新时间:..
点击次数:
论文类型:期刊论文
发表时间:2013-11-01
发表刊物:INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物:SCIE、Scopus
卷号:37
页面范围:202-205
ISSN号:1387-7003
关键字:Heptanuclear; Heterotrimetallic; Maleic acid; Bicapped trigonal bipyramid; Slow relaxation of the magnetization
摘要:With maleic acid as the ligand, a heterotrimetallic cluster {[Na(H2O)][Na2Cr2Tb3(mu(3)-OH)(6)(L)(6)(H2O)(17)]}center dot 16H(2)O (H2L = maleic acid) (1) bearing a bicapped trigonal bipyramidal [Na2Cr2Tb3] metal skeleton was synthesized and characterized. Magnetic measurements indicate that 1 displays overall ferromagnetic interactions and slow relaxation of the magnetization. (C) 2013 Elsevier B.V. All rights reserved.
上一条:Square and Butterfly Tetranuclear [Co(2)Ln(2)] Clusters Built from the Same Building Blocks but Displaying Different Magnetic Properties: Structural Variation by Means of Solvent and the Radii of Ln(3+) Ions
下一条:Pentanuclear {Cr(2)Ln(3)} (Ln = Dy, Tb) Heterometallic Clusters Based on an Amino Acid Ligand: Slow Relaxation of Magnetization and Substitution Reactions