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张国权
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Potentiodynamic Uniform Anchoring of Platinum Nanoparticles on N-Doped Graphene with Improved Mass Activity for the Electrooxidation of Ammonia

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论文类型: 期刊论文

第一作者: Zhou, Yufei

通讯作者: Zhang, GQ (reprint author), Dalian Univ Technol, Minist Educ, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn, Dalian 116024, Peoples R China.

合写作者: Zhang, Guoquan,Gong, Zheng,Shang, Xiuli,Yang, Fenglin

发表时间: 2016-04-01

发表刊物: CHEMELECTROCHEM

收录刊物: SCIE、EI

卷号: 3

期号: 4

页面范围: 605-614

ISSN号: 2196-0216

关键字: ammonia oxidation; electrochemistry; mass activity; N-doped graphene; platinum

摘要: Platinum nanoparticles anchored N-doped graphene (Pt/NG) catalysts are synthesized using a thermal annealing-potentiodynamic electrodeposition approach with melamine, graphene oxide, and PtCl62- as precursors. SEM, TEM, XRD, and XPS measurements indicate the relatively uniform and good dispersal of Pt nanoparticles on NG nanosheets. Compared to control catalysts of Pt nanoparticles loaded onto glassy carbon, undoped graphene and g-C3N4, the Pt/NG(1-1) catalyst (with a nominal mass ratio of melamine/graphene oxide of 1:1) shows the highest electrocatalytic activity towards the oxidation of ammonia among a series of Pt/NG catalysts. The mass activity of Pt/NG(1-1) catalyst is nearly 5.1times as high as that of Pt/glassy carbon. The excellent electrochemical performance of Pt/NG catalysts is attributed mainly to the considerable extent of pyridinic N and graphitic N-doping in the graphene network, which improves the dispersion state of Pt nanoparticles on the NG support, resulting in an apparent enhancement in mass activity.

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