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论文类型：期刊论文

第一作者：Xu, Lei

通讯作者：Zhang, GQ (reprint author), Dalian Univ Technol, Sch Environm Sci & Technol, MOE, Key Lab Ind Ecol & Environm Engn, Linggong Rd 2, Dalian 116023, Peoples R China.

合写作者：Zhang, Guo-quan,Yuan, Guang-en,Liu, Hai-yan,Liu, Jia-dong,Yang, Feng-lin

发表时间：2015-01-01

发表刊物：RSC ADVANCES

收录刊物：SCIE、EI、Scopus

卷号：5

期号：29

页面范围：22533-22543

ISSN号：2046-2069

摘要：In this study, an aerobic membrane bioreactor (MBR) equipped with anthraquinone-disulphonate/polypyrrole (AQDS/PPY) composite modified polyester (PT) flat membrane serving as the cathode of a dual-chamber microbial fuel cell (MFC) was developed for wastewater treatment, energy recovery and membrane fouling mitigation. Various physicochemical characteristic parameters were investigated to determine the surface properties of the AQDS/PPY/PT membrane. During most of the operation period, the chemical oxygen demand and NH4+-N removal efficiencies of this novel MFC-MBR coupled system averaged 92.5% and 70.6%, respectively. Over the hydraulic retention time of 11.58 h and the external resistance of 1000 Omega, a maximum power density of 0.35 W m(-3) and a current density of 2.62 A m(-3) were obtained, meanwhile, the membrane fouling mitigation achieved the best status the H2O2 concentration in membrane effluent also reached the highest value of 2.1 mg L-1. The effective membrane fouling mitigation was attributed mainly to the continuous self-generated bio-electricity of MFC, which not only accelerates the back-diffusion of negative charged foulants away from the membrane surface through the electrostatic repulsion, but also realizes membrane chemical cleaning through the in situ electrogenerated H2O2 and even (OH)-O-center dot radicals on the membrane surface and/or inside the membrane pore from the self-sustainable heterogeneous electro-Fenton process. Though the electricity recovery of the MFC-MBR coupled system was much lower than other high-output MFC systems, this study provided a new insight into the membrane anti-fouling mechanism and will arouse extensive interests to explore more high-efficiency catalytic membrane materials to maximize power output and minimize membrane fouling.