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论文类型：期刊论文

发表时间：2020-03-01

发表刊物：MOLECULAR CATALYSIS

收录刊物：EI、SCIE

卷号：483

ISSN号：2468-8231

关键字：Desilicated zeolites; Acidity tailoring; Phosphorous modification; Glycerol dehydration

摘要：Developments in microporous zeolites-base catalysts have evidenced the necessity of acidity tailoring in order to meet the exact requirements of specific reactions, which can be achieved by the post-modifications by various promoters. Compared to the elaborate works on the microporous counterparts, few studies have been reported for the post-modification of desilicated zeolites. In this work, the desilicated MFI zeolites with hierarchical porosities were subjected to the secondary post-modification by phosphorous promoter. It is demonstrated that both hierarchical structure and surface silanols are closely associated with the alterations of acidity and structure of phosphorous-containing moieties. Their catalytic consequences on the dehydration of glycerol to acrolein were also studied.