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Formation of NaH Molecules in the Lowest Rovibrational Level of the Ground Electronic State via Short-Range Photoassociation

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Indexed by:期刊论文

Date of Publication:2015-01-01

Journal:COMMUNICATIONS IN COMPUTATIONAL PHYSICS

Included Journals:SCIE、Scopus

Volume:17

Issue:1

Page Number:79-92

ISSN No.:1815-2406

Key Words:Short-range photoassociation; NaH molecule; rovibrational state

Abstract:The formation of NaH molecules in the lowest rovibrational level of the ground electronic state is investigated using a pump-dump photoassociation (PA) scheme. In short-range region, two colliding atoms Na and H are efficiently associated into the NaH molecule in the rovibrational vertical bar 0,0 > state of the ground electronic state via the intermediately rovibrational vertical bar 10,1 > state of the excited electronic state. The changes of populations with the electric field amplitudes, frequency detunings, dump pulse duration and delay time between two laser pulses are calculated and discussed. The PA probability reaches 0.623 with a high state-selectivity.

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