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  • 马红卫 ( 副教授 )

    的个人主页 http://faculty.dlut.edu.cn/2013011003/zh_CN/index.htm

  •   副教授   博士生导师   硕士生导师
论文成果 当前位置: 中文主页 >> 科学研究 >> 论文成果
Synthesis and characterization of in-chain silyl-hydride functional SBR and self-crosslinking elastomer

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论文类型:期刊论文
发表时间:2012-12-01
发表刊物:CHINESE CHEMICAL LETTERS
收录刊物:SCIE、ISTIC、CSCD、Scopus
卷号:23
期号:12
页面范围:1419-1422
ISSN号:1001-8417
关键字:4-Vinyiphenyldimethylsilanol; Functional in-chain sily-hydride copolymer; Self-crosslinking elastomers
摘要:Functional in-chain silyl-hydride (Si-H) SBR copolymers of 4-vinyiphenyldimethylsilanol (VPDMS) and butadiene were synthesized by living anionic polymerization, in which active group Si-H was not lost and its content was controllable. Corresponding self-crosslinking elastomers were obtained by hydrosilation of Si-H group with vinyl bonds in chain. The copolymers and elastomers were characterized by H-1 NMR, size exclusion chromatography (SEC), Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), and thermogravimetry analysis (TGA) techniques. (C) 2012 Yang Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

 

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