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Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers.

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Indexed by:期刊论文

Date of Publication:2018-02-21

Journal:Molecules (Basel, Switzerland)

Included Journals:SCIE、PubMed

Volume:23

Issue:2

ISSN No.:1420-3049

Key Words:Lewis pair polymerization,block copolymers,brush copolymers,click reaction,organocatalytic ring-opening polymerization

Abstract:Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, "thiol-ene" click reaction and organocatalytic ring-opening polymerization of lactide.

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