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论文类型： 期刊论文

发表时间： 2018-07-01

发表刊物： CHEMPLUSCHEM

收录刊物： SCIE

卷号： 83

期号： 7,SI

页面范围： 577-581

ISSN号： 2192-6506

关键字： electrochemistry; electrodeposition; oxidation; nickel; water splitting

摘要： Developing low-cost, effective, and durable oxygen-evolution catalysts (OECs) is still a huge challenge owing to the uphill thermodynamic reaction and the involvement of a four-electron and four-proton kinetics process. Herein, a facilely prepared NiCoFe(OH)(x)/NiOOH/NF electrode affords current densities of 10 and 100 mA cm(-2) at overpotentials of 223 and 254 mV, respectively, and a Tafel slope as low as 33.5 mVdec(-1) in 1 M KOH, which is superior to NiCoFe(OH)(x)/NF electrodes electrodeposited with a traditional method. This electrode also displays surprisingly high durability at a current density of 50 mA cm(-2) for over 50 hours under alkaline conditions. Component analysis and an electrochemical study revealed that the catalytic activity enhancement of this newly prepared electrode is mainly attributed to the formation of the electrically conductive NiOOH interlayer.