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论文类型：期刊论文
发表时间：2016-02-01
发表刊物：FUNCTIONAL MATERIALS LETTERS
收录刊物：SCIE、EI、Scopus
卷号：9
期号：1
ISSN号：1793-6047
关键字：Metal-organic framework; trinuclear zinc cluster; pillar-layered framework; photoluminescent property
摘要：A novel 3D metal-organic framework (MOF) {[Zn-3(bpdc)(3) (p-4-bpmb)](DMF)(2)}(n) (1) (H(2)bpdc = biphenyl-4,4'-dicarboxylic acid; p-4-bpmb = 1,4-bis(pyridine-4-ylmethoxy) benzene) has been solvothermally synthesized and structurally characterized. Compound 1 exhibits a 3D pillar-layered framework based on the trinuclear {Zn-3} building blocks, consisting of Zn-dicarboxylate layers and bipyridyl-derivative pillars. Furthermore, it features three-fold interpenetrating 8-connected hex-type topology. In addition, its thermal stability and luminescent property have also been investigated.