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Metal-organic frameworks (ZIF-67) as efficient cocatalysts for photocatalytic reduction of CO2: the role of the morphology effect

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Indexed by:期刊论文

Date of Publication:2018-03-21

Journal:JOURNAL OF MATERIALS CHEMISTRY A

Included Journals:SCIE、EI

Volume:6

Issue:11

Page Number:4768-4775

ISSN No.:2050-7488

Abstract:Metal-organic frameworks (MOFs), ZIF-67, with different morphologies were synthesized via a solvent-induced method at room temperature. The photocatalytic performances towards the reduction of CO2 were evaluated by using ZIF-67 materials as cocatalysts cooperating with a ruthenium-based complex as the photosensitizer. It has been demonstrated that the two-dimensional ZIF-67 with a leaf-like morphology exhibited the best photocatalytic activity and stability due to the highest CO2 adsorption capability and efficient electron transfer from the excited [Ru(bpy)(3)](2+) to ZIF-67.

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