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Gold-Palladium-Alloy-Catalyst Loaded UiO-66-NH2 for Reductive Amination with Nitroarenes Exhibiting High Selectivity


Indexed by:期刊论文

Date of Publication:2018-05-15


Included Journals:SCIE



Page Number:5092-5097

ISSN No.:2365-6549

Key Words:Au-Pd alloy; metal-organic frameworks; reductive amination; UiO-66-NH2

Abstract:Au Pd alloy catalysts were successfully loaded into amine-functionalized metal-organic framework (MOF, UiO-66-NH2) via direct absorption/reduction method. The existence of Pd in the alloy was revealed by using in situ fourier transform infrared spectroscopy (FTIR) with CO as probe molecules. The X-ray diffraction (XRD) and transmission electron microscopy (TEM) results demonstrated the Au Pd alloys were well dispersed within the robust UiO-66-NH2. Au Pd alloy nanoparticles with low Pd content were well dispersed within UiO-66-NH2 and exhibited high stability and selectivity for N-benzylaniline (98%) in the direct reductive amination with benzaldehyde and nitrobenzene.

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