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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：大连理工大学莱斯特国际学院副院长
性别：男
毕业院校：波鸿大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区精细化工国家重点实验室E段221
联系方式：+86-411-84986487
电子邮箱：jinxuan.liu@dlut.edu.cn
Highly oriented MOF thin film-based electrocatalytic device for the reduction of CO2 to CO exhibiting high faradaic efficiency
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论文类型：期刊论文
发表时间：2016-01-01
发表刊物：JOURNAL OF MATERIALS CHEMISTRY A
收录刊物：SCIE、EI
卷号：4
期号：40
页面范围：15320-15326
ISSN号：2050-7488
摘要：A monolithic, highly electrochemically efficient Re-based metal-organic framework (MOF) thin film has been deposited onto a conductive FTO electrode by liquid-phase epitaxy. The X-ray diffraction (XRD) analysis reveals the presence of a highly oriented film grown exclusively along the [001] direction. This epitaxially-grown SURMOF exhibits an extremely high faradaic efficiency of 93 +/- 5% when operated as an electrocatalyst for the reduction of CO2 to CO. In addition, the obtained current densities of the high-quality monolithic coatings exceed 2 mA cm(-2), a value at least one order of magnitude larger than that reported for previous electrocatalytically active MOF thin films.