崔淼

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高级工程师

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化学学院

办公地点:校部化学楼434

联系方式:0411-84706292

电子邮箱:mcui@dlut.edu.cn

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Study on the oxidation transformation of hexamethyleneimine in a confined region of zeolites

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论文类型:期刊论文

第一作者:Zhang, Shaoqing

通讯作者:Cui, M; Meng, CG (reprint author), Dalian Univ Technol, Sch Chem, Dalian 116024, Peoples R China.

合写作者:Cui, Miao,Zhang, Yifu,Mu, Yang,Lv, Tianming,Zheng, Jiqi,Zhao, Jing,Liu, Xiaoyu,Meng, Changgong

发表时间:2017-05-15

发表刊物:MICROPOROUS AND MESOPOROUS MATERIALS

收录刊物:SCIE、EI

卷号:244

页面范围:158-163

ISSN号:1387-1811

关键字:MOR; AFI; Hexamethyleneimine; Oxidation; C-13 NMR

摘要:Two kinds of zeolites (mordenite and AlPO4-5, with MOR and AFI topology, respectively) have been synthesized using hexamethyleneimine (HMI) as structure directing agent. It is found that HMI is incorporated intact in its protonated form in MOR and AFI. Furthermore, the oxidation of HMI restricted in the two zeolites by H2O2 has been studied. Analysis of FT-IR, Raman spectra, TG/DTA, EA and C-13 MAS NMR show that the restricted HMI molecules are changed into saturated hydrocarbons and some other amines in AFI, whereas unchanged in MOR. The adsorption tests illustrated that the as-synthesized samples and their oxidized products have high adsorption capacity for Ni(II). This work opens new opportunities for further research of molecular reactions on the inorganic hybrids, and provides a new idea for the application of SDAs present in molecular sieves. (C) 2017 Elsevier Inc. All rights reserved.