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论文类型：期刊论文

发表时间：2020-04-15

发表刊物：APPLIED SURFACE SCIENCE

收录刊物：EI、SCIE

卷号：509

ISSN号：0169-4332

关键字：Electrocatalysis; Oxygen reduction reaction; Porous carbon; ZnS; Heteroatom doping

摘要：Developing low cost, environmentally friendly and high efficiency oxygen reduction reaction (ORR) electrocatalysts is critical for clean energy conversion and storage devices including fuel cells and metal-air batteries. Herein, we developed a facile method to doping N, S and ZnS into carbon framework simultaneously. The N, S co-doping and extra ZnS active sites could prominently enhance the ORR performance of the carbon. The optimized sample ZnS@NC-3 exhibit an onset potential of 0.94 V and a half-wave potential of 0.84 V, which is comparable to 20 wt% PVC. In addition, the methanol tolerance and cycle ability are obvious superior than that of PVC. Moreover, when used as electrocatalysts for Zn-air battery, the battery exhibits an open circuit voltage of 1.524 V, a high specific capacity of 736 mA h g(-1) and a max power density of 176 mW cm(-2), demonstrating its great potential for clean energy conversion.