陈绍云

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高级工程师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:工业催化. 化学工艺

办公地点:大连理工大学西部校区化工实验楼B219

联系方式:高新区凌工路2号大连理工西校区化工实验楼B219 Tel:0411-84986322

电子邮箱:chensy@dlut.edu.cn

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咪唑衍生物辅助合成金属有机骨架MIL-101及CO2吸附性能

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发表时间:2022-10-10

发表刊物:化工进展

期号:7

页面范围:1808-1815

ISSN号:1000-6613

摘要:Metal-organic framework,MIL-101 was directly synthesized by the hydrothermal method using 2-methylimidazole,4-methylimidazole or 2-ethyl-4-methylimidazole as additive. The influence of synthesis condition on the products was investigated. The samples were characterized by XRD, N2-adsorption,SEM and UV-vis and were evaluated by CO2-adsorption in a dynamic adsorption device. MIL-101 samples synthesized presented well-defined octahedral morphology and uniform distribution of particles size. Synthesis temperature was lower than 180℃ and the highest yield of MIL-101 sample was 70%. The CO2 adsorption capability of MIL-101 synthesized by 4-methylimidazole was 313 mg/g under 1.0MPa.

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