刘程

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研究员

博士生导师

硕士生导师

任职 : 高分子材料系副系主任

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:高分子材料. 高分子化学与物理. 功能材料化学与化工

办公地点:大连理工大学西部校区化工实验楼A407室

联系方式:Tel.: 0411-84986191

电子邮箱:liuch1115@dlut.edu.cn

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Preparation, Morphologies, and Properties of Positively Charged Quaternized Poly(phthalazinone ether sulfone ketone) Nanofiltration Membranes

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论文类型:期刊论文

发表时间:2009-08-05

发表刊物:JOURNAL OF APPLIED POLYMER SCIENCE

收录刊物:SCIE、EI、Scopus

卷号:113

期号:3

页面范围:1389-1397

ISSN号:0021-8995

关键字:quaternized poly(phthalazinone ether sulfone ketone); nanofiltration; membrane performance and morphology; thermal stability

摘要:Positively charged quaternized poly(phthalazinone ether sulfone ketone) (QAPPESK) nanofiltration (NF) membranes were prepared from chloromethylated poly(phthalazinone ether sulfone ketone) by the dye/wet phase inversion method with N-methyl-2-pyrrolidone (NMP) and N,N-dimethylacetamide (DMAc) as solvents. The effects of the ratio of NMP to DMAc, the evaporation time, the evaporation temperature, and the coagulation temperature on membrane performance were evaluated by the orthogonal design method. The results showed that the optimal preparation conditions were an NMP/DMAc ratio of 2/8, an evaporation time of 5 min at 70 degrees C, and a coagulation temperature lower than 5 degrees C. The effects of the additive type and concentration on the QAPPESK NF membrane cross-section morphology and performance were investigated in detail. Furthermore, QAPPESK NF membranes exhibited good thermal stability with stable membrane performance for 120 h at 60 degrees C. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 113: 1389-1397, 2009