个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 大连理工大学膜科学与技术研究开发中心主任
性别:女
毕业院校:中国科学院大连化物所
学位:博士
所在单位:化工学院
学科:化学工程. 膜科学与技术. 生物医学工程
联系方式:hgaohong@dlut.edu.cn
电子邮箱:hgaohong@dlut.edu.cn
Coordtna Catalysts on Polymerization of alpha,omega-Dienes Using Single-Site Meta
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论文类型:期刊论文
第一作者:Pan, Yu
通讯作者:He, GH (reprint author), Dalian Univ Technol, Sch Petr & Chem Engn, State Key Lab Fine Chem, Panjin 124221, Peoples R China.
合写作者:Zhao, Xiuxiu,Xu, Xiaowei,He, Gaohong
发表时间:2016-01-01
发表刊物:MINI-REVIEWS IN ORGANIC CHEMISTRY
收录刊物:SCIE
卷号:13
期号:5
页面范围:349-362
ISSN号:1570-193X
关键字:alpha,omega-Dienes; coordination polymerization; half-metallocene complexes; metal complexes; metallocene complexes; single-site metal catalysts
摘要:As a type of important monomers, cc,co-dienes can be (co)polymerized to afford the polymers with various microstructures. The cyclopolymerization of cc,co-dienes performs as an efficient method to obtain the cyclopolyolefins, which usually exhibit remarkable properties, such as high transparency, good mechanical properties, high glass transition temperature, etc.. Moreover, incomplete cyclopolymerization of cw-dienes affords the polymers bearing pendant vinyl groups, which can be modified by post-polymerization modification strategy to generate the functional polymers. Therefore, polymerization of cw-dienes has attracted extensive attention in both industrial and academic researches during recent decades. Through years of development, numerous single-site metal catalysts for coordination polymerization of cc,co-dienes have been reported, concerning group 3 metals, group 4 metals and some late transition metals. So, the aim of this review is to highlight these single-site metal catalysts which are used for coordination polymerization of cw-dienes.