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论文类型：期刊论文

发表时间：2017-08-17

发表刊物：ADVANCED SYNTHESIS & CATALYSIS

收录刊物：SCIE、Scopus

卷号：359

期号：16

页面范围：2723-2728

ISSN号：1615-4150

关键字：allyl pinacolborate; allylation; catalysis; palladium; regioselectivity

摘要：The palladium-catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate is reported in this work. Chloromethylarenes smoothly reacted with allyl pinacolborate, producing para-allylated dearomatization products or para-allylated arenes in satisfactory to good yields. 2-(Chloromethyl)thiophenes and 2-(chloromethyl)furans bearing substituents on the 5-positions also smoothly reacted with allyl pinacolborate, producing the 5-allylated dearomatization products in satisfactory yields.