个人信息Personal Information
副研究员
博士生导师
硕士生导师
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:精细化工. 应用化学. 无机化学
联系方式:0411-84986476
电子邮箱:zhaol@dlut.edu.cn
个人简介Personal Profile
赵亮,理学博士,副教授,博士生导师。
2008年获得大连理工大学工学学士学位,并保送本校精细化工国家重点实验室(师从段春迎教授)。2011年国家留学基金委公派美国University of Massachusetts联合培养,2014年获得大连理工大学理学博士学位。随后加入大连理工大学精细化工国家重点实验室科技部创新人才推进计划创新团队和教育部“仿生识别与荧光传感”创新团队。主要从事功能化金属−有机限域空间超分子体系的构筑及仿生催化研究。2017年入选大连市高层次人才创新支持计划,同年作为团队骨干荣获大连市青年五四奖章(集体)。2018、2021年连续入选大连理工大学星海人才培育计划。先后主持国家自然科学基金委面上项目、青年项目和中国博士后科学基金,作为团队骨干参与国家自然科学基金重点项目、科技部重点基础研究发展计划(973计划)子课题以及国家重点研发计划子课题。在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nature Commun.等国际期刊上发表学术论文50余篇,申请/授权国家发明专利10余件。受邀J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem、Adv.Mater.等国际期刊审稿人。
研究方向:
1、金属-有机笼状配合物的组装及光催化与仿生催化
2、金属-有机笼与天然酶超分子体系协同催化级联反应
3、功能金属-有机框架材料(MOFs)的构筑与仿生催化
4、手性金属-有机笼状配合物的设计组装与不对称催化
热诚欢迎有志于投身科研事业的同学踊跃加盟,同时,团队长期招收博士后,有意者请发送简历至zhaol@dlut.edu.cn,期待您的真诚合作。
荣誉称号:
1、大连理工大学“星海人才培育计划”— 星海优青(2018年、2021年)
2、大连市高层次人才“创新支持计划”— 青年科技之星(2017年)
3、大连市青年五四奖章(集体,2017年)
教学科研奖励:
1、辽宁省自然科学学术成果奖一等奖(2015、2018、2019年)
2、辽宁省教学成果奖一等奖(2020年)
代表性论文:
37. Zeming Wang, Qiang Song, Cheng He, Pengyu Feng, Liang Zhao,* and Chunying Duan, Naphthalene-Based Donor−Acceptor Covalent Organic Frameworks as Electron Distribution Regulator for Boosting Photocatalysis under Green Light Irradiation, Chem. Commun., 2024, DOI: 10.1039/D4CC00910J.
36. Jianwei Wei, Liang Zhao,* Yu Zhang, Gang Han, Cheng He, Chong Wang, and Chunying Duan,* Enzyme Grafting with a Cofactor-Decorated Metal–Organic Capsule for Solar-to-Chemical Conversion, J. Am. Chem. Soc., 2023, 145(12), 6719−6729.
35. Guanfeng Ji, Liang Zhao,* Yang Tang, Songtao Liu, Yefei Wang, Cheng He, and Chunying Duan, Ultrathin Two-Dimensional Cerium-Based Metal−Organic Framework Nanosheet that Boosts Selective Oxidation of Inert C(sp3)−H Bond through Multiphoton Excitation, Small, 2023, 19(26), 2300597.
34. Yu Zhang, Liang Zhao,* Jianwei Wei, Guanfeng Ji, Huali Wang, Cheng He, Lehua Zhao, and Chunying Duan,* Dye-Binding Metal–Organic Cage for Highly Efficient Multiphoton Activation of C(sp3)−H Bonds, ACS Mater. Lett., 2023, 5(8), 2263−2269.
33. Yefei Wang, Liang Zhao,* Songtao Liu, Guanfeng Ji, Cheng He, Yang Tang, and Chunying Duan, A Mixed-Component Metal−Organic Framework for Boosting Synergistic Photoactivation of C(sp3)−H and Oxygen, ACS Appl. Mater. Interfaces, 2023, 15(13), 16744−16754.
32. Yang Tang, Guanfeng Ji, Hanning Li, Hui Gao, Cheng He, Liang Zhao* and Chunying Duan, Ligand-Regulated Photoinduced Electron Transfer within Metal−Organic Frameworks for Efficient Photocatalysis, Inorg. Chem. Front., 2023, 10(18), 5439−5451.
31. Jianwei Wei, Liang Zhao,* Yu Zhang, Peng Zhou, Guangzhou Liu, and Chunying Duan, Light-Switched Selective Catalysis with NADH Mimic Functionalized Metal–Organic Capsules, Chem. Commun., 2023, 59(1), 71−74.
30. Guanfeng Ji, Liang Zhao,* Jianwei Wei, Junkai Cai, Cheng He, Zenggang Du, Wei Cai, and Chunying Duan,* A Metal−Organic Framework as a Multiphoton Excitation Regulator for the Activation of Inert C(sp3)−H Bonds and Oxygen, Angew. Chem. Int. Ed., 2022, 61(2), e202114490. (Hot Paper, Editor’s Highlights)
29. Guanfeng Ji, Liang Zhao,* Yefei Wang, Yang Tang, Cheng He, Songtao Liu, and Chunying Duan, A Binuclear Cerium-Based Metal−Organic Framework as an Artificial Monooxygenase for the Saturated Hydrocarbons Aerobic Oxidation with High Efficiency and High Selectivity, ACS Catal., 2022, 12(13), 7821−7832. (Cover Paper)
28. Junkai Cai, Liang Zhao,* Yanan Li, Cheng He, Chong Wang, and Chunying Duan,* Binding of Dual-Function Hybridized Metal−Organic Capsule to Enzymes for Cascade Catalysis, JACS Au, 2022, 2(7), 1736−1746. (Highlights)
27. Yefei Wang, Liang Zhao,* Guanfeng Ji, Cheng He, Songtao Liu, and Chunying Duan, Vanadium(VIV)-Porphyrin-Based Metal−Organic Frameworks for Synergistic Bimetallic Activation of Inert C(sp3)−H Bonds, ACS Appl. Mater. Interfaces, 2022, 14(2), 2794−2804.
26. Yang Tang, Liang Zhao,* Guanfeng Ji, Yu Zhang, Cheng He, Yefei Wang, Jianwei Wei, and Chunying Duan, Ligand Regulated Metal−Organic Frameworks for Synergistic Photoredox and Nickel Catalysis, Inorg. Chem. Front., 2022, 9(13), 3116−3129. (Cover Paper)
25. Liang Zhao,* Wei Cai, Guanfeng Ji, Jianwei Wei, Zenggang Du, Cheng He, and Chunying Duan, Anthraquinone-Based Metal−Organic Framework as a Bifunctional Photocatalyst for C−H Activation, Inorg. Chem., 2022, 61(25), 9493−9503.
24. Liang Zhao,* Zenggang Du, Guanfeng Ji, Yefei Wang, Wei Cai, Cheng He, and Chunying Duan, Eosin Y-Containing Metal−Organic Framework as a Heterogeneous Catalyst for Direct Photoactivation of Inert C−H Bonds, Inorg. Chem., 2022, 61(19), 7256−7265.
23. Junkai Cai, Liang Zhao,* Cheng He, Yanan Li, and Chunying Duan,* A Host−Guest Semibiological Photosynthesis System Coupling Artificial and Natural Enzymes for Solar Alcohol Splitting, Nat. Commun., 2021, 12(1), 5092. (Editor’s Highlights)
22. Yefei Wang, Zhen Zhou, Liang Zhao,* Cheng He, Wenlong Sun, and Chunying Duan,* Ir-Porphyrin-Based Metal−Organic Framework as a Dual Metalloand Photocatalyst for Inert Alkyl C(sp3)−H Bond Activation and Direct Functionalization, ACS Appl. Mater. Interfaces, 2021, 13(9), 10925−10932.
21. Liang Zhao,* Shaoshuai Chu, Junkai Cai, Jianwei Wei, Yanan Li, Chunying Duan, Metal−Organic Triangles with NADH Mimics for Photocatalytic Hydrogen Production, Chinese J. Inorg. Chem., 2021, 37(5), 769−777.
20. Yanan Li, Liang Zhao,* Junkai Cai, Chunying Duan, Coumarin-Based Metal−Organic Cage for Recognition of Glucosamine, Fine Chemicals, 2021, 38(10), 2004−2011.
19. Liang Zhao,# Junkai Cai,# Yanan Li, Jianwei Wei, and Chunying Duan,* A Host−Guest Approach to Combining Enzymatic and Artificial Catalysis for Catalyzing Biomimetic Monooxygenation, Nat. Commun., 2020, 11(1), 2903. (Editor’s Highlights)
18. Jianwei Wei, Liang Zhao,* Cheng He, Sijia Zheng, Joost N. H. Reek, and Chunying Duan,* Metal−Organic Capsules with NADH Mimics as Switchable Selectivity Regulators for Photocatalytic Transfer Hydrogenation, J. Am. Chem. Soc., 2019, 141(32), 12707−12716.
17. Liang Zhao, Xu Jing, Xuezhao Li, Xiangyang Guo, Le Zeng, Cheng He,* Chunying Duan, Catalytic Properties of Chemical Transformation within the Confined Pockets of Werner-Type Capsules, Coord. Chem. Rev., 2019, 378, 151−187. (Highly Cited)
16. Junkai Cai, Liang Zhao,* Jianwei Wei, Cheng He, Saran Long, Chunying Duan,* Negatively Charged Metal−Organic Hosts with Cobalt Dithiolene Species: Improving PET Processes for Light−Driven Proton Reduction Through Host−Guest Electrostatic Interactions, Chem. Commun., 2019, 55(59), 8524−8527. (Cover Paper)
15. Sijia Zheng, Liang Zhao*, Jianwei Wei, Cheng He, Guangzhou Liu, Chunying Duan, A New Cobalt Triangular Prism Supramolecular Flask: Encapsulation of a Quinhydrone Cofactor for Hydrogenation of Nitroarenes with High Selectivity and Efficiency, Inorg. Chem. Commun., 2019, 109, 107558.
14. Xu Jing, Cheng He, Liang Zhao, and Chunying Duan,* Photochemical Properties of Host−Guest Supramolecular Systems with Structurally Confined Metal−Organic Capsules, Acc. Chem. Res., 2019, 52(1), 100−109. (Cover Paper, Highly Cited)
13. Liang Zhao, Jianwei Wei, Jing Zhang, Cheng He,* Chunying Duan,* Encapsulation of a Quinhydrone Cofactor in the Inner Pocket of Cobalt Triangular Prisms: Combined Light−Driven Reduction of Protons and Hydrogenation of Nitrobenzene, Angew. Chem. Int. Ed., 2017, 56(48), 15284−15288.
12. Liang Zhao, Jianwei Wei, Junhua Lu, Cheng He,* Chunying Duan,* Renewable Molecular Flasks with NADH Models: Combination of Light−Driven Proton Reduction and Biomimetic Hydrogenation of Benzoxazinones, Angew. Chem. Int. Ed., 2017, 56(30), 8692−8696.
11. Liang Zhao, Jian Wang, Pengyan Wu, Cheng He, Xiangyang Guo, Chunying Duan,* DHPA−Containing Cobalt-Based Redox Metal−Organic Cyclohelicates as Enzymatic Molecular Flasks for Light−Driven H2 Production, Sci. Rep., 2017, 7, 14347.
10. Liang Zhao, Jianwei Wei, Feili Zhang, Cheng He, Sijia Zheng, Chunying Duan,* Redox−Active Copper Triangles as an Enzymatic Molecular Flask for Light−Driven Hydrogen Production, RSC Adv., 2017, 7(77), 48989−48993.
9. Liang Zhao, Xiang Wu, Xiaofeng Wang, Chunying Duan, Hongyan Wang, Amol Punjabi, Yang Zhao, Yuanwei Zhang, Zuoshang Xu, Haifeng Gao,* Gang Han,* Development of Excipient−Free Freeze−Dryable Unimolecular Hyperstar Polymers for Efficient siRNA Silencing, ACS Macro Lett., 2017, 6(7), 700−704.
8. Lu Yang, Liang Zhao, Zhen Zhou, Cheng He,* Hui Sun and Chunying Duan, A Thiourea-Functionalized Metal–Organic Macrocycle for the Catalysis of Michael Additions and Prominent Size-Selective Effect, Dalton Trans., 2017, 46(12), 4086–4092.
7. Regino Mercado-Lubo, Yuanwei Zhang, Liang Zhao, Kyle Rossi, Xiang Wu, Yekui Zou, Antonio Castillo, Jack Leonard, Rita Bortell, Dale L. Greiner, Leonard D. Shultz, Gang Han,* and Beth A. McCormick,* A Salmonella Nanoparticle Mimic Overcomes Multidrug Resistance in Tumours, Nat. Commun. 2016, 7(1), 12225.
6. Liang Zhao, Yulu Chu, Cheng He, Chunying Duan,* Fluorescent Detection of RDX within DHPA−Containing Metal−Organic Polyhedra, Chem. Commun., 2014, 50(26), 3467−3469.
5. Liang Zhao, Yang Liu, Cheng He,* Jian Wang, Chunying Duan,* Coordination−Driven Nanosized Lanthanide "Molecular Lanterns" as Luminescent Chemosensors for the Selective Sensing of Magnesium Ions, Dalton Trans., 2014, 43(1), 335−343.
4. Liang Zhao, Artem Kutikov, Jie Shen, Chunying Duan, Jie Song,* and Gang Han,* Stem Cell Labeling using Polyethylenimine Conjugated (α-NaYbF4:Tm3+)/CaF2 Upconversion Nanoparticles, Theranostics, 2013, 3(4), 249−257. (Cover Paper)
3. Cheng He, Jian Wang, Liang Zhao, Tao Liu, Jing Zhang and Chunying Duan,* A Photoactive Basket-Like Metal–Organic Tetragon Worked as an Enzymatic Molecular Flask for Light Driven H2 Production, Chem. Commun., 2013, 49(6), 627−629.
2. Jie Shen, Liang Zhao, Gang Han,* Lanthanide-Doped Upconverting Luminescent Nanoparticle Platforms for Optical Imaging-Guided Drug Delivery and Therapy, Adv. Drug Delivery Rev., 2013, 65, 744−755. (Highly Cited)
1. Liang Zhao, Siyi Qu, Cheng He,* Rong Zhang and Chunying Duan, Face-Driven Octanuclear Cerium(IV) Luminescence Polyhedra: Synthesis and Luminescent Sensing Natural Saccharides, Chem. Commun., 2011, 47(33), 9387−9389.