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论文类型：期刊论文

发表时间：2019-01-31

发表刊物：SEPARATION AND PURIFICATION TECHNOLOGY

收录刊物：SCIE

卷号：209

页面范围：1016-1026

ISSN号：1383-5866

关键字：Selective catalytic oxidation of ammonia; Hollow ZSM-5; Ag-0 species; Metal-encapsulated

摘要：Hollow ZSM-5 encapsulating Ag particles (Ag/ZSM-5-OH) have been successfully synthesized, characterized and tested in NH3-SCO reaction. In comparison with Ag/Al2O3 and Ag/ZSM-5-OH, Ag/ZSM-5 catalyst displayed the lowest T-100 (110 degrees C), much higher TOF and the lowest E-a. Although fresh Ag/ZSM-5-OH catalyst showed the relatively low NH3 conversion, its reaction cycles stability was significant higher than that of Ag/Al2O3 and Ag/ ZSM-5 catalysts. The hollow structure of ZSM-5 zeolite could prevent sintering and/or leaching of Ag particles during NH3 oxidation process. Zeolite membrane formed during dissolution-recrystallization process in the surface of hollow ZSM-5 could offer good separation properties for SO2. So SO2 did not diffuse into the hollow structure to be poisoned Ag catalyst, finally induced the outstanding SO2/H2O resistance.