先进催化材料研究组 (Advanced Catalytic Materials  Research Group, ACM-RG)

组训：进取、创新、求实、求是！！！

研究组倡导不断进取，勇于创新，脚踏实地，实事求是，和深入洞悉事物内在规律和本质的科研作风。

“先进催化材料”课题组（Advanced Catalyic Materials Research Group, ACM-RG），主要致力于精细化工原料及中间体的绿色制造和新能源转化相关催化新材料的理性设计和可控构筑。主要包括：精细化工原料及中间体的催化清洁合成、低碳分子和生物质模型分子的催化转化、光催化分解水制氢、电催化分解水制氢、光催化有机合成、电催化有机合成等。

催化是化工的基石，是破解能源和环境问题的金钥匙。为应对人类所面临的能源和环境两大挑战，结合我国化工、能源的可持续发展战略及环境保护，依托化学工程与技术国家重点一级学科和工业催化、应用化学国家重点二级学科，成立“先进催化材料”研究组，坚持基础研究和应用研究并重的发展模式，主要开展构筑特定结构和功能催化材料的新方法、新概念及催化活性位调控，揭示其构效关系研究，创制高效催化剂。研究组可以招生报考大连理工大学的工业催化、能源化工或应用化学 三个专业的博士研究生，以及工业催化、能源化工 专业的硕士研究生。欢迎各地有志之博士生和硕士生加盟本研究组，也欢迎来研究组从事博士后研究工作；大家共同成长，携手发展，共创美好未来）。

本组的优势：

1）作为化环生学部工业催化系最年轻的教授，除具有较为丰富的科研阅历，还兼具年轻老师所具有的旺盛的精力，从而保证了对研究生的有效指导

2）从2017年1月1日起，发表论文，第一作者都给学生，不管是硕士生，还是博士生。这对学生就业和未来发展的重要性是不言而喻的

3）作为研究组负责人，学生科研工作，可以直接与我讨论决定，更节时、更高效，学生自由翱翔的空间越大

硕士研究生报考时，可以选择工业催化或者能源化工专业所列的任意研究方向；博士研究生报考时，可以选择工业催化、能源化工或应用化学专业所列的任意研究方向。

有意加入本研究组的学生，欢迎与我联系：zkzhao@dlut.edu.cn.

欢迎访问：

https://www.x-mol.com/groups/zhao_zhongkui

 先进催化材料课题组，可以招生报考大连理工大学的工业催化、能源化工、应用化学 三个专业的博士，及工业催化 、 能源化工  专业的硕士研究生（注：报考时，选择相关专业的任意研究方向均可）。欢迎各地有理想、有抱负的博士生和硕士生加盟本研究组（欢迎具有催化、物理化学、材料化学、有机化学、无机化学等不同学科背景的学生加盟），也欢迎来研究组从事博士后研究工作；大家共同成长，携手发展，共创美好未来！！！    科研无坦途。但，遇到困难时，我们可以一起并肩作战、披荆斩棘、克敌制胜、攻克难关！！！

为了学生的未来发展，自2017年1月1日起，发表论文，研究生为论文第一作者（注：适用于所有研究生，包括硕士生和博士生）。

 

近年来代表性成果：

[1] Ting Zhang,¹ Zhe Sun,¹ Shiyan Li,² Baojun Wang,³ Yuefeng Liu,^2,* Riguang Zhang,^3,* and Zhongkui Zhao^1,* Regulating electron configuration of single Cu sites via unsaturated N,O-coordination for selective oxidation of benzene to phenol, Nature Communications, 2022, 13, 6996. DOI: 10.1038/s41467-022-34852-y (IF=17.694）

[2] Ting Zhang,† Di Zhang,† Xinghua Han,‡ Ting Dong,‡ Xinwen Guo,† Chunshan Song,†,‖ Rui Si,*,§ Wei Liu,# Yuefeng Liu,*,# and Zhongkui Zhao*,† Preassembly Strategy To Fabricate Porous Hollow Carbonitride Spheres Inlaid with Single Cu–N₃ Sites for Selective Oxidation of Benzene to Phenol. Journal of the American Chemical Society, 2018,140 16936-16940. (IF=16.383)

[3] XueZhang^a,1, Weiwei Yu^a,1, Ting Zhang^a, Siyuan He^a, Wantong Zhao^b, Baojun Wang^b, Yuefeng Liu ^c,* Benxue Zou^d, Riguang Zhang^b,* and Zhongkui Zhao^a,* Adjacent diatomic Cu1N3/Mo1S2 entities decorated carbon nitride for markedly enhanced photocatalytic hydrogen generation. Chemical Engineering Journal, 2023, xxx, xxxx. xxx-xxxx. DOI: 10.1016/j.cej.2023.142470. (IF=16.744)

[4] Mengzhao Liu,^a Zhe Sun,^a Chaofan Zhang,^a Shiyan Li,^b Chaozhen He,^c Yuefeng Liu,*^b and Zhongkui Zhao*^a Multi-interfacial engineering of Coil-like NiS-Ni₂P/Ni hybrid to efficiently boost electrocatalytic hydrogen generation in alkaline and neutral electrolyte,  Journal of Materials Chemistry A, 2022, 10, 13410-13417. DOI: 10.1039/D2TA03021G (IF=14.511)

[5] Ting Zhang,^a,1  Zhenyu Xie,^a,1 Luozhen Jiang,^b,1 Wantong Zhao,^c Shuo Cao,^d Baojun Wang,^c Rui Si,^b Riguang Zhang,^c,* Yuefeng Liu,^d,* and Zhongkui Zhao^a,* Selective transfer hydrogenation coupling of nitroaromatics to azoxy/azo compounds by electron-enriched single Ni-N4 sites on mesoporous N-doped carbon, Chemical Engineering Journal, 2022, 443, 136416. xxx-xxxx. DOI: 10.1016/j.cej.2022.136416 (IF=16.744)

[6] Yu Zhang,^§,† Weiwei Yu,^§,† Shuo Cao,^§,‡,‖ Zhe Sun,^§,† Xiaowa Nie,^† Yuefeng Liu^‡ and Zhongkui Zhao*^,†, Photocatalytic Chemoselective Transfer Hydrogenation of Quinolines to Tetrahydroquinolines on Hierarchical NiO/In₂O₃-CdS Microspheres, ACS Catalysis, 2021, 11,13408–13415. (IF=13.700)

[7] Mengzhao Liu,‡^a Zhe Sun,‡^a Shiyan Li,‡^b,c Xiaowa Nie,‡^a Yuefeng Liu,^b Erdong Wang,^b and Zhongkui Zhao*^a, Hierarchical superhydrophilic/superaerophobic CoMnP/Ni2P nanosheets-based microplates arrays for enhanced overall water splitting, Journal of Materials Chemistry A, 2021, 9, 22129-22139. (IF=14.511)

[8] Ting Zhang, Di Zhang, Xinghua Han, Ting Dong, Xinwen Guo, Chunshan Song, Rui Si*, Wei Liu, Yuefeng Liu*, and Zhongkui Zhao*, Addition to “Preassembly Strategy To Fabricate Porous Hollow Carbonitride Spheres Inlaid with Single Cu–N₃ Sites for Selective Oxidation of Benzene to Phenol”, Journal of the American Chemical Society, 2022, 144, 1066. (IF=16.383)

[9] Qin Zhou+, Guifang Ge+, Zhanglong Guo+, Yuefeng Liu, and Zhongkui Zhao*, Poly(Imidazolium-Methylene)-Assisted Grinding Strategy to Prepare Nanocarbons-Embedded Network Monoliths for Carbocatalysis, ACS Catalysis, 2020, 10, 14604-14614.  (IF=13.700)

[10] Weiwei Yu, Ting Zhang, and Zhongkui Zhao*, Garland-like intercalated carbon nitride prepared by an oxalic acid-mediated assembly strategy for highly-efficient visible-light-driven photoredox catalysis, Applied Catalysis B: Environmental, 2020, 278, 119342. DOI: 10.1016/j.apcatb.2020.119342.  (IF=24.319)

[11] Guanchao Wang,†,§ Ting Zhang,†,§ Weiwei Yu,†,§ Rui Si,*,‡ Yuefeng Liu,*, # and Zhongkui Zhao*,†, Modulating Location of Single Copper Atoms in Polymeric Carbon Nitride for Enhanced Photoredox Catalysis, ACS Catalysis, 2020, 10(10), 5715-5722 (IF=13.700) (Highlighted by cover)

[12] Weiwei Yu, Xin Shan, and Zhongkui Zhao*,  Unique nitrogen-deficient carbon nitride homojunction prepared by a facile inserting-removing strategy as an efficient photocatalyst for visible light-driven hydrogen evolution, Applied Catalysis B: Environmental, 2020, 269, 118778.  DOI: 10.1016/j.apcatb.2020.118778  (IF=24.319)

[13] Di Zhang, Yongle Guo, Zhongkui Zhao*, Porous defect-modified graphitic carbon nitride via a facile one-step approach with significantly enhanced photocatalytic hydrogen evolution under visible light irradiation. Applied Catalysis B: Environmental, 2018, 226, 1-9. (IF=24.319) (ESI 高被引用论文)

[14] Zhongkui Zhao,* Yitao Dai, Jinhan Lin and Guiru Wang, Highly-Ordered Mesoporous Carbon Nitride with Ultrahigh Surface Area and Pore Volume as a Superior Dehydrogena-tion Catalyst. Chemistry of Materials, 2014, 26, 3151-3161. (IF=10.508) （ESI 1% 高被引论文）

[15] Zhongkui Zhao* and Yitao Dai, Nanodiamond/carbon nitride hybrid nanoarchitecture as an efficient metal-free catalyst for oxidant- and steam-free dehydrogenation. Journal of Materials Chemistry A, 2014, 2, 13442-13451. (IF=14.511)

[16] Zhongkui Zhao*, Ronghua Jin, Ting Bao, Xiaoli Lin, Guiru Wang, Mesoporous ceria-zirconia supported cobalt oxide catalysts for CO preferential oxidation reaction in excess H₂. Applied Catalysis B: Environmental, 2011,110, 154-163. (IF=24.319)

[17] Ting Bao, Zhongkui Zhao*, Yitao Dai, Xiaoli Lin, Ronghua Jin, Guiru Wang, Turghun Muhammad, Supported Co₃O₄-CeO₂ catalysts on modified activated carbon for CO preferential oxidation in H₂-rich gases. Applied Catalysis B: Environmental, 2012, 119-120, 62-73. (IF=24.319)

[18] John N. Kuhn, Zhongkui Zhao, Larry G. Felix, Rachid B. Slimane, Chun W. Choi, Umit S. Ozkan*, Olivine catalysts for methane- and tar- steam reforming. Applied Catalysis B: Environmental, 2008, 81, 14-26. (IF=24.319)

[19] Zhongkui Zhao*, Xiaoli Lin, Ronghua. Jin, Guiru Wang, Turghun Muhammad, MO_x (M = Mn, Fe, Ni or Cr) improved supported Co₃O₄ catalysts on ceria-zirconia nanoparticulate for CO preferential oxidation in H₂-rich gases. Applied Catalysis B: Environmental, 2012, 115-116, 53-62. (IF=24.319)

[20] Zhongkui Zhao,* Hongling Yang, Yu Li and Xinwen Guo, Cobalt-modified molybdenum carbide as an efficient catalyst for chemoselective reduction of aromatic nitro compounds. Green Chemistry, 2014, 16, 1274-1281. (IF=11.034)

[21] Zhongkui Zhao,* Yitao Dai, Guifang Ge, Xinwen Guo and Guiru Wang, Facile simultaneous defect producing and O,N-doping of carbon nanotube with unexpected catalytic performance for clean and energy-saving production of styrene. Green Chemistry, 2015, 17, 3723-3727. (IF=11.034) (highlighted as back cover)

[22] Weizuo Li, Zhongkui Zhao*, Guiru Wang, Modulating Morphology and Textural Properties of ZrO₂ for Supported Ni Catalysts towards Dry Reforming of Methane. AIChE Journal, 2017, 63 (7), 2900-2915. (IF=4.167). (Top 1 Journal in Chem Eng)

[23] Zhongkui Zhao*, Yitao Dai, Guifang Ge, and Guiru Wang, Efficient Tuning of Microstructure and Surface Chemistry of Nanocarbon Catalysts for Ethylbenzene Direct Dehydrogenation. AIChE Journal, 2015,61 :2543-2561. (IF=4.167) (Top 1 Journal in Chem Eng)

[24] Zhongkui Zhao*, J. H. Lin, G. Wang, T. Muhammad. Novel Co-Mn-O Nanosheet Catalyst for CO Preferential Oxidation toward Hydrogen Purification. AIChE Journal, 2015, 61, 239-252. (IF=4.167) (Top 1 Journal in Chem. Eng.)

[25] Weiwei Yu, Xinwen Guo, Chunshan Song, Zhongkui Zhao*, Visible-light-initiated one-pot clean synthesis of nitrone from nitrobenzene and benzyl alcohol over CdS photocatalyst. Journal of Catalysis, 2019, 370, 97-106. (IF=8.047)

[26] Di Zhang, Xinghua Han, Ting Dong, Xinwen Guo, Chunshan Song, Zhongkui Zhao*, Promoting effect of cyano groups attached on g-C₃N₄ nanosheets towards molecular oxygen activation for visible light-driven aerobic coupling of amines to imines. Journal of Catalysis, 2018, 366, 237-244. (IF=8.047)

[27] Zhongkui Zhao*, Yitao Dai, Ting Bao, Renzhi Li, Guiru Wang, Direct alkenylation of aromatics with phenylacetylene over supported H₃PW₁₂O₄₀ catalysts as a clean and highly efficient approach to producing α-arylstyrenes. Journal of Catalysis, 2012, 288: 44-53. (IF=8.047)

[28] Qijun Hou, Bumei Zheng, Chenguang Bi, Jimei Luan, Zhongkui Zhao*, Hongchen Guo, Guiru Wang, Zongshi Li, Liquid-phase cascade acylation/dehydration over various zeolite catalysts to synthesize 2-methyl anthraquinone through an efficient one-pot strategy. Journal of Catalysis, 2009, 268, 376-383. (IF=8.047)

[29] Xiaojing Wei^§,†, Guifang Ge^§,†, Weiwei Yu^§,†, Hongchen Guo†, Xinwen Guo†, Chunshan Song*,^‡,‖, and Zhongkui Zhao*,† Plastering Sponge with Nanocarbon-Containing Slurry to Construct Mechanically Robust Macroporous Monolithic Catalysts for Direct Dehydrogenation of Ethylbenzene, ACS Applied Materials & Interfaces,2022, 14(17) :19315-19323. (IF=10.383)

[30] Guifang Ge, Xinwen Guo, Chunshan Song, and Zhongkui Zhao*. Reconstructing Supramolecular Aggregates to Nitrogen Deficient g-C3N4 Bunchy Tubes with Enhanced Photocatalysis for H₂ Production. ACS Applied Materials & Interfaces, 2018, 10 :18746-18753. (IF=10.383)