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Palladium/Amine Complex Catalyzed Suzuki-Miyaura Reaction of Arylboron Compounds in Water

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Indexed by:期刊论文

First Author:Li, Xinmin

Correspondence Author:Liu, C (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Linggong Rd 2, Dalian 116024, Peoples R China.

Co-author:Liu, Chun,Wang, Lei,Ye, Qing,Jin, Zilin

Date of Publication:2017-05-15

Journal:CHEMISTRYSELECT

Included Journals:SCIE

Volume:2

Issue:14

Page Number:4016-4020

ISSN No.:2365-6549

Key Words:Aryltrifluroboroates; MIDA boronates; Palladium/amine complex; Suzuki reaction; Water

Abstract:An air-stable palladium/amine complex Pd(OAc)(2)[(i-Pr)(2)NH](2) was first synthesized and well characterized. This complex demonstrated high efficiency for the Suzuki-Miyaura reactions of hetero) aryl halides with arylboronic acids, potassium aryltri-fluoroborotes and aryl N-methyliminodiacetic acid boronates in water without any additives.

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