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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学
电子邮箱：cliu@dlut.edu.cn
扫描关注
A simple and efficient approach for the palladium-catalyzed ligand-free Suzuki reaction in water
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论文类型：期刊论文
发表时间：2012-01-01
发表刊物：GREEN CHEMISTRY
收录刊物：SCIE、Scopus
卷号：14
期号：11
页面范围：2999-3003
ISSN号：1463-9262
摘要：A general and efficient protocol is described for the palladium-catalyzed ligand-free and aerobic Suzuki reaction in water in the absence of any additive. The results demonstrate that the base played a crucial role in the high efficiency. The Pd(OAc)(2)/(i-Pr)(2)NH/H2O system showed the highest catalytic activity towards the Suzuki reaction of a wide range of aryl halides bearing hydrophilic or hydrophobic groups.