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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学
电子邮箱：cliu@dlut.edu.cn
扫描关注
Very Fast, Ligand-Free and Aerobic Protocol for the Synthesis of 4-Aryl-Substituted Triphenylamine Derivatives
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论文类型：期刊论文
发表时间：2011-06-01
发表刊物：EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
收录刊物：SCIE
期号：16
页面范围：3009-3015
ISSN号：1434-193X
关键字：Synthetic methods; Palladium; Boron; Cross coupling; Amines
摘要：A fast, convenient and ligand-free protocol for the synthesis of a series of 4-aryl-substituted triphenylamine derivatives by a palladium-catalysed aerobic Suzuki reaction of aryl halides with [4-(diphenylamino)phenyl] boronic acid in aqueous iPrOH is described. Importantly, both aryl bromides and heteroaryl halides afforded good to excellent yields under mild conditions.